期刊
CHEMICAL PHYSICS LETTERS
卷 371, 期 5-6, 页码 568-575出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S0009-2614(03)00313-0
关键词
-
A total of 400 trajectories for the photodissociation, CH3CHO --> CH3 + HCO, on the T-1 potential surface have been calculated using the direct ab initio molecular dynamics method at the UB3LYP/cc-pVDZ level of theory. It was predicted that the product CH3 is neither vibrationally nor rotationally excited and HCO is vibrationally not excited but rotationally excited. The averaged HCO rotational energy was calculated to be 1.1 kcal mol(-1), which is 15.1% of the available energy, 7.3 kcal mol(-1). The present result agrees with experiment within just a few percent of the observed data. (C) 2003 Elsevier Science B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据