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卷 44, 期 18, 页码 3687-3689出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(03)00685-3
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Structural similarity has been used to identify multifunctional templates for topochemically controlled solid-state photodimerisation. By examination of co-crystal structures of 4,4'-bipyridine with various acids, tricarballylic acid and 1,2,4,5-benzenetetracarboxylic acid have been identified as supramolecular templates for the alignment in the solid-state of 1,2-bis(4-pyridyl)ethylene. As a result, photodimerisation in the solid-state proceeds smoothly and with high yield. (C) 2003 Elsevier Science Ltd. All rights reserved.
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