期刊
NANOTECHNOLOGY
卷 14, 期 5, 页码 566-570出版社
IOP Publishing Ltd
DOI: 10.1088/0957-4484/14/5/316
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We have used computer simulations to investigate the potential of triptycene-based rotors mounted on the Si(100)-2 x 1 surface. Two concepts are explored for attaching the triptycene to the Si surface: -COOH and -OH groups. We find the -COOH produces an axle with too many degrees of freedom, creating too flexible a coupling to the substrate. By contrast, the calculations suggest that the -OH coupling should provide a useful stiff axle.
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