期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 345, 期 5, 页码 560-563出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200303010
关键词
(E)-2-(alkylthio)alka-1,3-diene; allene; diselenide; disulfide; hydride transfer; rhodium
Reaction of dialkyl disulfides or diselenides with allenes is catalyzed by a rhodium-phosphine complex and trifluoromethanesulfonic acid giving (E)-2-alkylthio(seleno)-1,3-dienes and (E)-2-alkylthio(seleno)-2-alkenes. Unlike the reaction of alkynes, the reaction of allene is accompanied by hydride transfer.
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