期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 6, 期 5, 页码 486-490出版社
ELSEVIER
DOI: 10.1016/S1387-7003(03)00021-2
关键词
ruthenium(II) triphenylarsine complexes; tetradentate Schiff bases; catalytic oxidation study; intermediate ruthenium-oxo species
Ruthenium(II) complexes of the type [Ru(CO)(B)(L)] (B = AsPh3, pyridine, piperidine or morpholine; L = dianion of tetradentate Schiff bases) have been synthesized and characterized by physico-chemical methods. These complexes are found to be effective catalysts in the oxidation of primary and secondary alcohols using N-methylmorpholine-N-oxide as oxidant. The catalytic activity of these triphenylarsine complexes have been compared with that of triphenylphosphine complexes and with similar ruthenium(III) complexes. The formation of high valent Run+2=O species as catalytic intermediate is proposed for the catalytic processes. (C) 2003 Elsevier Science B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据