期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 637, 期 -, 页码 106-111出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2015.02.220
关键词
Nanostructured materials; Metals and alloys; Mechanochemical processing; Magnetic materials; Microwave absorption
资金
- National Natural Science Foundation of China [11204225]
- Equipment Development pre-research shared Technology Fund Project [9140A10031212QT69120]
- Top Talents Lead Cultivation Project of Hubei Province
- Yellow Crane talents plan of Wuhan municipal government
- Postdoctoral Science Foundation of China [2012M521483, 2013T60751]
- University Industry Cooperation project from guangdong province [2011A090200083]
Controlling the microstructures such as particle shape, grain size (< D >) and internal strain () of magnetic absorbents are of importance for the construction of broadband microwave absorbing materials (MAMs). Here we have developed a heating wet ball-milling method to tune the aspect ratio (a(r)), < D > and of the flaky carbonyl iron powders (CIPs) so as to achieve optimized microwave absorbing properties. In our protocol, when the milling temperature (T) exceeds 250 degrees C, the heat effects dominate over the deformation effects, deteriorating the electromagnetic performances due to the rapid growth up of < D >. When T is below 250 degrees C, the deformation effects play a dominant part. In this condition, the constantly accumulate and ar decrease with T, decreasing the relative complex permeability. As a result, controlling T cannot enlarge < D > and , but only increase a(r). This comes from the competition of the grain growth effect and deformation effect at different temperatures. The as-obtained flaky CIPs are a good candidate absorbent for broadband MAMs of thin thickness. The heating wet ball-milling method proposed here, as a simple and effective way to control the particle shape, grain size and internal strain of CIPs, can be easily extended to the fabrication of other high performance magnetic absorbents. (C) 2015 Elsevier B.V. All rights reserved.
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