期刊
CORROSION SCIENCE
卷 45, 期 5, 页码 923-940出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0010-938X(02)00208-1
关键词
corrosion; immersion; diffusion; mathematical modelling; mild steel
In the mathematical modelling of the 'general' corrosion of mild and low alloy steels and of some other metals oxygen diffusion through the corrosion products to the corroding surface controls the rate of corrosion at least during some period in the corrosion-time behaviour relationship. Under slightly different theoretical assumptions various early authors derived expressions for this phase. It was usually assumed the derived relationship applied from initial immersion. Only very limited laboratory support for the derived relationships exists. They have been applied to field data for atmospheric corrosion but with constants and exponents modified empirically. In the present paper the theory is reviewed and extended. It is argued that diffusion control cannot apply from first immersion and that this provides considerably greater freedom to mathematical modelling. Allowance is made for non-uniform corrosion product density and permeability and for loss of corrosion product. Recent detailed 'at-sea' experimental observations obtained on the Eastern Australian seaboard are applied to test the theory for mild steel. It is shown that the most likely competing mathematical relationships produce relatively similar results. The derived relationship is fitted to literature data to deduce its temperature dependence. (C) 2002 Elsevier Science Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据