期刊
JOURNAL OF CHROMATOGRAPHY A
卷 995, 期 1-2, 页码 233-238出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S0021-9673(03)00543-0
关键词
water analysis; solid-phase extraction; molecular imprinting; 4-chlorophenols; 4-nitrophenol
Three polymers have been synthesised using 4-chlorophenol (4-CP) as the template, following different protocols (non-covalent and semi-covalent) and using different functional co-monomers, 4-vinylpyridine (4-VP) and methacrylic acid (MAA). The polymers were evaluated to check their selectivity as molecularly imprinted polymers (MIPs) in solid-phase extraction (SPE) coupled on-line to liquid chromatography. The solid-phase extraction procedure using MIPs (MISPE), including the clean-up step to remove any interferences, was optimised. The 4-VP non-covalent polymer was the only one which showed a clear imprint effect. This MIP also showed cross-reactivity for the 4-chloro-substituted phenols and for 4-nitrophenol (4-NP) from a mixture containing the 11 priority EPA (Environmental Protection Agency) phenolic compounds and 4-chlorophenol. The MIP was applied to selectively extract the 4-chloro-substituted compounds and 4-NP from river water samples. (C) 2003 Elsevier Science B.V. All rights reserved.
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