期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 9, 期 9, 页码 2123-2128出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200204571
关键词
alkenes; heterocycles; peroxides; radical reactions
Stereoselective styryl derivatives have been prepared based on radical substitution (addition-elimination) of heterocycles or cyclohydrocarbons units to (E)-beta-nitrostyrenes 1 using a common radical initiator benzoyl peroxide. High reactivity and selectivity with wide substrate scope were attained by using this easy methodology. The reactions using easily obtained and one-pot potential starting materials gave excellent trans-selectivity with medium to high yields in all cases. Synthetic utility of this approach has been demonstrated by the preparation of various trans-styryl derivatives.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据