期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 68, 期 11, 页码 4546-4548出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo034138m
关键词
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The addition of alpha-haloalkyl Grignard reagents to benzaldehyde occurs with simple diastereoselectivity substantially higher than that of the corresponding lithium reagents. Reaction in the presence of dimethyl-aluminum chloride suppresses subsequent Oppenauer oxidation of the resulting Mg-alkoxides by excess benzaldehyde.
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