期刊
MOLECULAR DIVERSITY
卷 7, 期 2-4, 页码 97-106出版社
SPRINGER
DOI: 10.1023/B:MODI.0000006803.99656.8c
关键词
boronic acids; combinatorial chemistry; high throughput chemistry; microwaves; oxidative Heck; palladium
类别
资金
- Swedish Natural Science Research Council
- Swedish Foundation for Strategic Research
The useful and selective reactivity of arylboronic acids makes them favourite building blocks for many modern organic chemistry applications like the metal-mediated formation of C-C, C-O, C-N, and C-S bonds. This report describes oxidative Heck coupling reactions of arylboronic acids and olefins, which were conveniently and rapidly (5-30 min) carried out under air with temperature-controlled microwave heating. Different reaction conditions were investigated with regard to both microwave heating capability and chemical productivity. Copper(II) acetate was identified as a microwave compatible reoxidant of Pd(0). The scope and limitations of this high-speed chemistry protocol with diverse olefins and organoboronic acids are discussed.
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