期刊
JOURNAL OF MOLECULAR STRUCTURE
卷 654, 期 1-3, 页码 47-53出版社
ELSEVIER
DOI: 10.1016/S0022-2860(03)00179-0
关键词
crystal engineering; supramolecular structure; isonicotinate acid; hydrothermal synthesis
A three-dimensional supramolecular compound [Ni(IN)(2)(H2O)(4)] 1 has been rationally designed and synthesized by hydrothermal method, and the structure was characterized with elemental analysis, FT-IR spectrum and X-ray diffractometer. In the packing structure, the stronger intermolecular O-(HO)-O-... hydrogen-bonded and pi-pi stacking interactions are the most significant factors of controlling the novel supramolecular sheet fashion for the title compound. The third-order non-linear optical property of compound 1 was also investigated, and it exhibits nicer reverse saturable absorption and self-focusing performance. (C) 2003 Elsevier Science B.V. All rights reserved.
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