期刊
PHYSICAL REVIEW LETTERS
卷 90, 期 25, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.90.256401
关键词
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First-principles calculations on p-type doping of the paradigm wide-gap ZnO semiconductor reveal that successful doping depends much on engineering a stable local chemical bonding environment. We suggest a cluster-doping approach in which a locally stable chemical environment is realized by using few dopant species. We explain two puzzling experimental observations, i.e., that monodoping N in ZnO via N-2 fails to produce p-type behavior, whereas using an NO source produces metastable p-type behavior, which disappears over time.
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