期刊
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
卷 159, 期 1, 页码 7-16出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/S1010-6030(03)00112-6
关键词
chromene; photochromism; kinetic studies; thermal bleaching rate constant; F-19 NMR
The synthesis and the optical properties of eleven new photochromic compounds of the diphenyl-chromene family containing different halogen substituents are reported. Kinetic studies under continuous irradiation indicate that for these compounds the bleaching of the merocyanines involves two first order processes. Fluoro-substitution of the phenyl ring(s) always leads to an increase in the fast rate constant, k(1), that is also found to increase on changing the halogen in the naphthalenic fragment from fluorine to chlorine and to bromine. F-19 NMR confirms the presence of isomers produced under irradiation. One of these isomers exhibits a great stability in solution. A single crystal X-ray diffraction study indicates that in 6-fluoro-2,2-bis(4'-fluorophenyl)-2H-benzo[h]chromene the two phenyl rings are orthogonal to each other and that the pyranic fragment deviates considerably from planarity. (C) 2003 Elsevier Science B.V. All rights reserved.
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