期刊
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
卷 39, 期 7, 页码 933-946出版社
MAIK NAUKA/INTERPERIODICA
DOI: 10.1023/B:RUJO.0000003181.02370.cf
关键词
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Addition of bromotrichloromethane and tetrachloromethane to alkenes in the presence of palladium(II) complexes begins with single-electron transfer from the palladium atom to polyhalomethane molecule, followed by fragmentation of the radical anion thus formed and generation of trichloromethyl radical. Halogen transfer to a carbon-centered radical arising from addition of trichloromethyl radical at the double bond occurs both from the polyhalomethane molecule and from halide palladium complex.
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