期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 649, 期 -, 页码 332-336出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2015.07.123
关键词
Solid solution; Cadmium; Zinc; Hydrogen production; Photocatalytic reforming; Glycerol
资金
- Brazilian research funding agency Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq) [442840/2014-4]
- Brazilian research funding agency Fundacao de Amparo a Pesquisa do Estado da Bahia (FAPESB) [APP0046/2011]
A simple sonochemical method for the preparation of Cd1-xZnxS solid solutions was successfully applied. The sonochemical method has shown to be fast, with low energy demand and allowed to obtain nano-sized particles. The obtained materials were characterized by XRD, EDX, SEM and DRS UV/vis. The Pt-loaded photocatalysts were evaluated in photoinduced reforming of glycerol under visible light irradiation (lambda > 418 nm). Pure CdS and solid solutions obtained by sonochemical method have shown photocatalytic activity with respect to hydrogen gas production. The maximum hydrogen evolution rate achieved was 239 mu mol g(-1) h(-1), when the solid solution Cd0.6Zn0.4S contaminated with gamma- Zn(OH)(2) was irradiated with visible light. (C) 2015 Elsevier B.V. All rights reserved.
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