期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 263, 期 1, 页码 296-305出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/S0021-9797(03)00125-5
关键词
emulsion; capillary number; viscosity; rheology
A new equation for the relative viscosity of infinitely dilute emulsions of noncolloidal droplets is proposed using the analogy between shear modulus and shear viscosity. In the limit of capillary number --> 0, the proposed equation reduces to the well-known Taylor viscosity law for infinitely dilute emulsions. Starting from the proposed equation for an infinitely dilute emulsion, new viscosity equations for concentrated emulsions are then developed using a differential scheme. The proposed equations for concentrated emulsions are evaluated in light of a large body of published experimental data on the viscosity of emulsions. (C) 2003 Published by Elsevier Science (USA).
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