4.7 Article

Polymethine dyes derived from boron complexes of, acetylhydroxycoumarins

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DYES AND PIGMENTS
卷 58, 期 1, 页码 41-46

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ELSEVIER SCI LTD
DOI: 10.1016/S0143-7208(03)00022-6

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3-acetyl-4-hydroxycoumarin; 8-acyl-7-hydroxycoumarins; difluoro[1,3-propanedionato-O,O ']boron derivatives; polymethine; dyes; NMR

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Novel dyes were obtained by condensation of boron derivatives of 3-acetyl-4-hydroxy- or 7-hydroxy-8-acylcoumarin with triethyl orthoformate of Fischer's aldehyde. The reaction of the former boron complexes with DMF followed by condensation of the resultant hemicyanine with dimethylquinolinium iodides furnished non-symmetric polymethine dyes with a quinoline its the terminal heterocyclic unit. (C) 2003 Elsevier Science Ltd. All rights reserved.

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