期刊
TETRAHEDRON LETTERS
卷 44, 期 28, 页码 5175-5178出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(03)01266-8
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In lipase-catalyzed asymmetrization of 1,3-propanediacetate no enantioselectivity was observed in conventional organic solvents, whereas in supercritical carbon dioxide (scCO(2)) enantioselectivities were observed up to 50% ee, which probably arose from a conformational changing of lipase at the active site due to a transformation of the amino group of lysine into carbamic acid. (C) 2003 Elsevier Science Ltd. All rights reserved.
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