期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 13, 页码 2406-2412出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200200677
关键词
polyoxometalates; molybdenum; N ligands; coordination chemistry
Anderson-type polyoxomolybdates [MMO6O18{(OCH2)(3)-CNH2}(2)](3-) (M = Mn-III, Fe-III) were prepared and structurally characterized. The tris(alkoxo) ligands are bound to the central heteroatom via their oxygen atoms. The corresponding compounds with M = Ni-II or Zn-II are not accessible since these cations have a preference for the amino functionality. The pendant amino groups of the manganese-containing derivative react with pyridinecarbaldehydes to give the corresponding imines. This provides new mono- and bidentate binding sites for metal cations. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据