Electronic properties of 4,4′,5,5′-tetramethyl-2,2′-biphosphinine (tmbp) in the redox series fac-[Mn(Br)(CO)3(tmbp)], [Mn(CO)3(tmbp)]2, and [Mn(CO)3(tmbp)]-:: Crystallographic, spectroelectrochemical, and DFT computational study