期刊
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
卷 221, 期 1-3, 页码 221-230出版社
ELSEVIER
DOI: 10.1016/S0927-7757(03)00138-9
关键词
mesoporous silica; non-ionic surfactant; adsorbent; copper; chromate
Heavy metals adsorbents were prepared by co-condensation of tetraethoxysilane and functionalized trialkoxysilane RSi(OR')(3). Functionalized porous silicas with aminopropyl (H2N(CH2)(3)-), [amino-ethylamino]propyl- (H2N-(CH2)(2)-NH(CH2)(3)), (2-aminoethylamino)-ethylamino]propyl (H2N-(CH2)(2)-NH-(CH2)(2)-NH(CH2)(3)-), and mercaptopropyl (HS-(CH2)(3)-) groups were synthesized using dodecylamine as structure directing agent. These materials have been characterized by elemental analysis, powder X-ray diffraction, nitrogen gas sorption, Fourier transform infrared and Raman spectroscopies and thermogravimetric analysis. These organo-silicas were prepared for use in the removal of heavy metal ions from aqueous solutions. Samples synthesized with [amino-ethylamino]propyl- and (2-aminoethylamino)ethylamino]propyl- functions show a high loading capacity for Cu2+, Ni2+, Co2+ and the anion Cr(VI). The sample synthesized with a mercaptopropyl function has a high loading capacity for Cd2+. (C) 2003 Elsevier Science B.V. All rights reserved.
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