期刊
JOURNAL OF POWER SOURCES
卷 122, 期 2, 页码 210-218出版社
ELSEVIER
DOI: 10.1016/S0378-7753(03)00429-4
关键词
alkaline polymer electrolyte; polyvinyl alcohol; poly(epichlorohydrin); ionic conductivity; Zn-air battery
Alkaline SPE was obtained from a blend of polyvinyl alcohol (PVA) and poly(epichlorohydrin) (PECH), PVA-PECH, by a solution-cast technique. The PVA host polymer is blended with PECH polymer to provide a polymer electrolyte with improved chemical and mechanical properties. The ionic conductivity of the PVA-PECH polymer electrolytes is between 10(-2) and 10(-3) S cm(-1) at room temperature when the blend ratio is varied from 1:0.2 to 1: 1. The PVA-PECH polymer was characterized by means of scanning electron microscopy, X-ray diffraction, stress-strain test, cyclic voltammetry, and a.c. impedance spectroscopy. It is found that the polymer electrolytes exhibit good mechanical strength and excellent chemical stability. The electrochemical performance of solid-state Zn-air batteries with various types of the blended polymer electrolyte films is examined by a galvanostatic discharge method. (C) 2003 Elsevier Science B.V. All rights reserved.
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