期刊
CHEMICAL GEOLOGY
卷 198, 期 1-2, 页码 21-31出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S0009-2541(02)00420-5
关键词
infrared spectroscopy; ammonium; muscovite; phengite
Single muscovite grains of different chemical composition (in particular Si-content from 3.05 to 3.69 per formulae unit (pfu)) and origin (metamorphic and granitic rocks) were analysed by infrared (IR) spectroscopy. Their ammonium concentrations were subsequently measured by capacitance manometry after extraction as N-2 using a sealed-tube combustion technique. The values range from 0 to 2203 ppm NH4+. Correlation between ammonium concentration and ammonium IR absorbance corresponding to NH4+ bending permits an assessment of the ammonium molecular absorptivity at 1430 cm(81430 epsilon(N-H)(1430) = 462 +/- 32 1 mol(-1) cm(-1)). In order to avoid uncertainties on thickness estimates using an optical technique, a relationship between sample thickness and IR absorbance was determined. Ammonium concentration of muscovite can be directly derived from its IR spectrum using the relationship [NH4+] (ppm) = 1142.5 x [A(N-H)(1430) - A(2514))/(A(1282) - A(2514))] - 606 where A(1282) ,A(N-H)(1430) and A(2514) are absorbances corresponding to wavenumbers 1282 (Si-O vibration peak), 1430 (NH4+ bending) and 2514 cm(-1) (silicate network vibration), respectively. The precision of ammonium concentration estimates using this method is better than 20% (2sigma) for muscovites thicker than 30 mum. This is independent of mineral composition, thus implying that the ammonium concentration vs. IR absorbance relationship is independent of the muscovite-celadonite solid solution. (C) 2002 Elsevier Science B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据