期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 107, 期 30, 页码 7391-7395出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp0340111
关键词
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Nanocrystalline films of Au, Ag, and Cu have been prepared at the toluene-water interface by the interaction of metal-triphenylphosphine complexes in the organic layer with partially hydrolyzed tetrakishydroxymethylphosphonium chloride in the aqueous layer. The nanocrystals have been characterized by a host of microscopic and spectroscopic techniques. The free-standing films could be transferred from the interface onto solid supports. Furthermore, films could be dissolved to yield either a hydrosol or an organosol with the help of appropriate surfactants.
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