期刊
NATURAL PRODUCT RESEARCH
卷 17, 期 4, 页码 269-274出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/1057563021000060158
关键词
hydrastine; microbial metabolite; NMR; circular dichroism; cytochrome P-450
The phthalideisoquinoline alkaloid (-)-beta-hydrastine is one of the main active constituents of the medicinal plant, Hydrastis canadensis, which is used in many dietary supplements intended to enhance the immune system. Treatment of hydrastine with the fermentation broth of Polyporous brumalis (ATCC 34487) as a model for mammalian metabolism, gave a new alkaloid, (1S)-hydroxyhydrastine. Structure elucidation was based primarily on NMR and chiroptical studies.
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