4.3 Article

Paradigms and paradoxes:: Accidental degeneracies, I:: Suppose the 2s and 2p orbitals were closer in energy.: How would organic chemistry be different?

期刊

STRUCTURAL CHEMISTRY
卷 14, 期 4, 页码 417-419

出版社

KLUWER ACADEMIC/PLENUM PUBL
DOI: 10.1023/A:1024410229577

关键词

orbital degeneracy; triplet ground states; ethylenedione; carbenes; carbon allotropes; carbon-carbon quadruple bond

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Hypothesized accidental orbital degeneracies, from origins other than symmetry, in the second principal quantum level lead to surprising new chemistry of carbenes, aromatic compounds, and, most interestingly, to a possible new allotrope of carbon. Consequences of degeneracies in the transition metals are hinted at.

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