期刊
STRUCTURAL CHEMISTRY
卷 14, 期 4, 页码 417-419出版社
KLUWER ACADEMIC/PLENUM PUBL
DOI: 10.1023/A:1024410229577
关键词
orbital degeneracy; triplet ground states; ethylenedione; carbenes; carbon allotropes; carbon-carbon quadruple bond
Hypothesized accidental orbital degeneracies, from origins other than symmetry, in the second principal quantum level lead to surprising new chemistry of carbenes, aromatic compounds, and, most interestingly, to a possible new allotrope of carbon. Consequences of degeneracies in the transition metals are hinted at.
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