期刊
POLYHEDRON
卷 22, 期 18, 页码 2581-2586出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0277-5387(03)00349-8
关键词
antiferromagnetic interaction; alkoxide; late transition metal; X-ray; molecular structure
Interaction of 4 equiv. CoCl2 with 6 equiv. of NaOC2H4OEt in toluene/HOC2H4OEt medium provided Co4Cl2(OC2H4OEt)(6) (1) with practically quantitative yield. Reaction of Co(acac)(2) with Ti(OMe)(4) in 1:1 ratio in toluene gave Co-4(OMe)(2)(acac)(6)(MeOH)(2) (2) with moderate yields. The same reaction for Zn(acac)(2) resulted in formation of Zn-4(OMe)(2)(acac)(6)(C7H8) (3), The structures of 1-3 contain planar tetranuclear cores of M-4(mu(3)-OR)(2)(mu(2)-OR)(4) type ([Ti(OMe)(4)](4) type structure), where the metal atoms are pentacoordinated in 1, hexacoordinated in 2, and both penta- and hexacoordinated in 3. The magnetic measurements have revealed competing ferromagnetic and antiferromagnetic interactions between the 4 Co(II) atoms in 1, but only ferromagnetic in 2. (C) 2003 Elsevier Ltd. All rights reserved.
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