期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 9, 期 15, 页码 3472-3479出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200204640
关键词
block copolymers; micelles; nanotechnology; supramolecular chemistry; terpyridines
The formation of asymmetric bis-complexes, based on terpyridine ligands and ruthenium ions, is described as a powerful tool for the self-assembly of polymer blocks end-functionalized with terpyridine units. This is illustrated in this contribution for the synthesis of amphiphilic metallo-supramolecular block copolymers, which are further used to produce aqueous micelles. Finally, the reversibility of the supramolecular bond opens new avenues for the preparation and manipulation of these nano-objects.
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