期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 68, 期 16, 页码 6264-6267出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo034477f
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The reaction of chiral sulfinimines 1c-g derived from aliphatic aldehydes with TMSCN in the presence of CsF gave alpha-amino nitriles in high diastereoselectivity and yield. alpha,beta-Diamino acid derivatives were also obtained in high diastereoselectivity from the reaction of 2-aziridinesulfinimines 1h and 1i followed by ring-opening of the products with thiophenol. The presence of hydrogen at the alpha-position of the C=N double bond is crucial in this TMSCN addition reaction.
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