The high-pressure local structure of zinc oxide has been studied at room temperature using combined energy-dispersive x-ray-diffraction and x-ray-absorption spectroscopy experiments. The structural parameter u and the lattice-parameter ratio c/a of the wurtzite phase is given as a function of pressure and compared with results from ab initio calculations based on a plane-wave pseudopotential method within the density-functional theory. It is shown that an accurate study of ZnO requires the explicit treatment of the d electrons of Zn as valence electrons. In good agreement with present calculations, our experimental data do not show any variation of u(P) in the low-pressure wurtzite phase between 0 and 9 GPa, pressure at which the phase transition to the rocksalt phase occurs. Moreover, no dramatic modification of the r-phase K-edge position up to similar to20 GPa is observed, indicating the absence of metallization. In view of all these results, theoretical models identifying the wurtzite-to-rocksalt transition as an homogeneous path are discussed.
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