期刊
JOURNAL OF APPLIED PHYSICS
卷 94, 期 5, 页码 3654-3656出版社
AMER INST PHYSICS
DOI: 10.1063/1.1600520
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Blueshifts in the ultraviolet absorption spectra have been observed in cerium oxide nanocrystallites. The mechanism of the absorption is a charge-transfer optical transition. The relationships among the blueshift, valence state of cerium ions, and the particle size are formulated. The blueshifts are well explained for diameters down to less than a few nanometers by the change in the electronic band structure. (C) 2003 American Institute of Physics.
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