Influence of cross-linked potato starch treated with POCl3 on DSC, rheological properties and granule size

Differential scanning calorimetry (DSC), rheological measurements and granule size analyses were performed to characterize the influence of phosphorylation substitution levels on the properties of cross-linked potato starch. Phosphorus oxychloride (POCl3) was used to produce the cross-linked potato starch. The levels of the reagent used for the reaction ranged between 40 and 5000 ppm (dwb). Storage (G') and loss (G) moduli were measured for a 5% (w/w) gelatinized starch dispersion stored at 20 degreesC for 24 h after heating at 85 degreesC for 30 min. The samples from 80 to 500 ppm were recognized as 'strong gel' systems, whereas native potato starch showed 'weak gel' behavior. Steady shear and dynamic viscoelastic properties of gelatinized starch dispersion were compared. Furthermore, granule mean diameter was measured by laser scattering for a 1% (w/w) dispersion heated at 85 degreesC for 30 min. The granules in the 100 ppm sample swelled to a maximum of about 2.6 times the native starch granule mean diameter. (C) 2003 Elsevier Ltd. All rights reserved.