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Relativistic configuration-interaction oscillator strength calculations with ab initio model potential wavefunctions

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IOP PUBLISHING LTD
DOI: 10.1088/0953-4075/36/17/306

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The relativistic configuration-interaction (CI) method with numerical Dirac-Fock wavefunctions generated using an ab initio model potential with non-integer outermost core shell occupation number to improve the efficiency of the CI representation of core-valence electron correlation, is used to calculate oscillator strengths for the lowest spin-allowed and spin-forbidden ns(2) S-1(0)-nsnp P-1(1), P-3(1) transitions in some systems with two valence electrons. The present results are compared with our earlier data obtained with core-valence correlation represented in the semiclassical core polarization picture.

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