期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 68, 期 19, 页码 7505-7508出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo0349375
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A new series of modular chiral ligands that are derived from amino acids were prepared and tested for their ability to catalyze the asymmetric addition of alkylzinc reagents to aromatic and aliphatic aldehydes. The ligands contain a tertiary amine, an amino acid side chain, and a carbamate or amide functional group. One ligand, which was synthesized from Ile, catalyzes the addition of diethylzinc to cyclohexanecarboxaldehyde in 99% ee.
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