期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 9, 期 18, 页码 4286-4294出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200305048
关键词
amidocarbonylation; domino reactions; Diels-Alder reactions; multicomponent reactions
The acid-catalyzed condensation chemistry of simple amides and aldehydes provides a highly prolific source of diverse reactants for irreversible follow-up reactions. Amide - aldehyde mixtures have been successfully employed in multicomponent syntheses of N-acyl alpha-amino acids (via palladium-catalyzed amidocarbonylation) and various cyclohexene, cyclohexadiene, and benzene derivatives (via the amide-aldehyde-dienophile (AAD) reaction).
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