Speciation of Cr(III) and Cr(VI) by nanometer titanium dioxide micro-column and inductively coupled plasma atomic emission spectrometry

A sensitive and selective method has been developed for the speciation of Cr(III) and Cr(VI) in natural water using a nanometer titanium dioxide micro-column (20 mm x 3.0 mm i.d.) and inductively coupled plasma atomic emission spectrometry (ICP-AES). Under the optimized conditions (pH 6.0, flow rate 1.0 ml min(-1)), Cr(III) was retained on the column, then eluted with 2.0 mol l(-1) HCl and determined by ICP-AES. Total chromium was determined after the reduction of Cr(VI) to Cr(III) by ascorbic acid as reducing reagent. The adsorption capacity of nanometer TiO2 for Cr(Ill) was found to be 7.6 mg g(-1). The detection limit for Cr(Ill) was 0.32 mug l(-1) and the relative standard deviation (R.S.D.) was 2.4% (n=11, C=100 mug l(-1)) with an enrichment factor of 50. The proposed method has been applied to the determination and speciation of chromium in natural water samples with satisfactory results. (C) 2003 Elsevier Science B.V. All rights reserved.