期刊
ELECTROCHEMICAL AND SOLID STATE LETTERS
卷 6, 期 10, 页码 A210-A213出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.1601373
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Because the rate of anodic deposition for manganese oxide is much larger than that for nickel oxide, the nickel content of binary Mn-Ni oxide can be increased by using a relatively positive potential region and a high Ni2+/Mn2+ ratio (10/1) in the deposition solution. The capacitive characteristics of this binary oxide in a mixed electrolyte consisting of 0.1 M Na2SO4 with pH 10.1 adjusted by 0.01 M NaOH are much more ideal than that measured in 0.1 M Na2SO4. The effects of introducing Ni oxide into the MnOx matrix on the capacitive performance are systematically investigated. The nanostructure of this Mn-Ni oxide deposit is demonstrated from the scanning electron microscopic morphology. (C) 2003 The Electrochemical Society.
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