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catena-(bis(μ2-1,3-bis(4-pyridyl)propane-N,N′)-diaqua-cobalt(II)) dinitrate 1,3-bis(4-pyridyl) propane monohydrate

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BLACKWELL MUNKSGAARD
DOI: 10.1107/S1600536803019330

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The hydrothermally prepared title compound, [Co(C26H28N4)(H2O)(2)]2NO(3).C13H14N2.H2O, (I), consists of infinite one-dimensional chains containing two independent Co2+ centers, each octahedrally coordinated by two water molecules and four bridging 1,3-bis(4-pyridyl)propane (bpp) ligands. The chains are linked into infinite two-dimensional layers by hydrogen bonding, via an uncoordinated bpp molecule, and further into a three-dimensional framework via interstitial nitrate anions and water molecules. (1) is isostructural to the Ni analog previously reported [Krishnamohan Sharma et al., (2000). Cryst. Eng. 3, 201-208].

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