期刊
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
卷 59, 期 -, 页码 M384-M386出版社
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S0108270103015786
关键词
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The title complex, diaquadipyridinelithium (N-methyl-p-tert-butyldihomoammoniocalix[4] arene-kappa(4) O) dioxouranium(VI) tripyridine solvate monohydrate, [Li(C5H5N)(2)(H2O)(2)][UO2( C46H58NO4)].3C(5)H(5)N.H2O, contains an 'internal' tetraphenoxide-coordinated uranyl complex of the macrocycle, in which the protonated N atom is involved in an intramolecular hydrogen bond with the uranyl oxo group located in the cavity. The Li+ ion is in a tetrahedral environment and its two water ligands are involved in hydrogen bonds with two phenoxide O atoms, two pyridine molecules and one water molecule. This arrangement is compared with those obtained previously for other homoazacalixarenes and also for homooxacalixarenes in the presence of alkali metal hydroxides.
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