Two new salts 2-phenyl imidazolium hydrogen cyclobutane-1,1-dicarboxylate 1, imidazolium hydrogen malonate 2, and two new co-crystals benzimidazole/succinic acid co-crystal (1:1) 3 and benzimidazole/isophthalic acid co-crystal (1:1) 4 were synthesized and characterized by X-ray crystallography in order to analyze their supramolecular architecture. The results are examined and compared with the structures present in the Cambridge Structural Database.
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