期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 90, 期 2, 页码 505-510出版社
WILEY
DOI: 10.1002/app.12687
关键词
crosslinking; resins; quaternized chitosan resin; chromium (VI); adsorption
An inverse emulsion method was used to prepare the chitosan microspheres, which were crosslinked with epichlorohydrin between the hydroxyl groups under protection of amino groups to obtain crosslinked chitosan resin. Further chemical modification with glycidyl trimethylammonium chloride was used to form the quaternary ammonium ion resin. The resin had different adsorption ability for the chromium (VI) in anionic forms from that of the crosslinked chitosan beads. The crosslinked chitosan resin exhibited maximum adsorption for chromium (VI) at pH 3.0 and the adsorption capacity decreased sharply above pH 6, whereas the adsorption capacities of quaternized chitosan resin were significant over pH 3 to 11. The quaternized resin was more efficient than the crosslinked chitosan resin in media of pH above 5. The complete removal of chromium from the solution of K2Cr2O7 was achieved with a column method using the quaternized chitosan resin, which was hard, and the decrease in pressure in the column was small. The breakthrough point of 10.0 mg L-1 chromium in quaternized resin column was 3200 mL g(-1) resin greater than 600 mL g(-1) resin in the crosslinked chitosan resin column. (C) 2003 Wiley Periodicals, Inc.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据