期刊
THERMOCHIMICA ACTA
卷 405, 期 1, 页码 85-91出版社
ELSEVIER
DOI: 10.1016/S0040-6031(03)00126-6
关键词
1-adamantanol; 2-adamantanol; 2-methyl-2-adamantanol; enthalpy of sublimation; saturated vapor pressure
The enthalpies of sublimation and the saturated vapor pressure of 1-adamantanol (1-Adol), 2-adamantanol (2-Adol) and 2-methyl-2-adamantanol (2-Me-2-Adol) were measured. Thermodynamic functions of the compounds under study in the ideal gas state between 100 and 1000 K were calculated by the statistical thermodynamic methods. The sets of wave numbers of normal vibrations for adamantanols were obtained by semi empirical calculation (MINDO3 I/I MNDO/d). The experimental entropies for gaseous adamantanols and the calculated values were in the satisfactory agreement. (C) 2003 Published by Elsevier Science B.V.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据