期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 68, 期 21, 页码 8256-8257出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo034961i
关键词
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The hetero-Diels-Alder reaction of an electron-deficient nitrile, p-toluenesulfonyl cyanide, with the silyl enol ether of cyclohexenone produced a hydrolytically sensitive [4 + 2] adduct in good yield. Use of Mander's reagent, ethyl cyanoformate, with the same diene, produced an unstable adduct. Hydrolysis of the tosyl cyanide adduct resulted in the isoquinuclidinone 2-aza[2.2.2]octa-3,5-dione as a crystalline compound in excellent yield from the nitrile.
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