期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 90, 期 4, 页码 940-946出版社
JOHN WILEY & SONS INC
DOI: 10.1002/app.12648
关键词
conducting polymers
Polythiophene (PTh) films were prepared by the electrochemical polymerization of thiophene in acetonitrile solution with boron fluoride-ethyl ether (BFEE) as the electrolyte. The electropolymerization. processes were investigated by cyclic voltammetry. The onset potential of the electropolymerization decreased dramatically with increasing BFEE proportion in the solution. The free-standing PTh films obtained were characterized by Founier transform infrared spectroscopy, scanning electron microscopy, and X-ray photoelectron microscopy. The influence of BFEE on the morphology and conductivity of the PTh films was also examined. The binary solvent solution consisted of acetonitrile (10 vol %) and BFEE (90 vol %), which turned out to be the optimal electrosythesis system, in which a current density of 1 mA/cm(2) and a monomer concentration of 50 mM were the optimal conditions for electropolymerization. The PTh film obtained under the optimized conditions had a high tensile strength of 60 MPa and a high conductivity of 153 S/cm. (C) Wiley Periodicals, Inc.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据