期刊
ELECTROCHEMISTRY COMMUNICATIONS
卷 5, 期 11, 页码 919-923出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2003.08.017
关键词
lithium-ion battery; elastomeric binder; alloy anode materials; tether model; crosslinking; adhesion strength
Recently, new electrode materials based on amorphous alloys have been proposed to replace the graphite-based anode materials for lithium-ion batteries. These alloys undergo colossal reversible volume expansions as lithium is added and removed from them electrochemically. We show that if the alloy particles in the electrode are strongly tethered to one another and to the current collector by an elastomeric binder that good capacity retention versus cycle number, in spite of 125% volume expansion and contraction, is possible. To obtain the required mechanical properties, the elastomeric polymer binder is crosslinked and also bonded to the electrode particles using a surface coupling agent. A stable specific capacity of about 800 mAh/g in a-Si0.64Sn0.36, corresponding to 125% volume change, was obtained with a poly(vinylidene fluoride-tetrafluoroethylene-propylene)-based elastomeric binder system. Further optimization of the binder system is expected to be possible. (C) 2003 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据