The effect of substrate temperature on the physical properties of tantalum oxide thin films grown by reactive radio-frequency sputtering

Thin films of TaOx were deposited on Si(1 0 0) by radio-frequency magnetron sputtering at substrate temperatures of 25, 100, 200, 300, 400, and 500 degreesC. The properties of TaOx thin films deposited with different oxygen-to-argon gas ratios and substrate temperatures were evaluated. The results show that the films with lowest leakage current density were obtained at ambient temperature with an oxygen mixture ratio (OMR) of 60% and the oxygen-to-tantalum ratio has a minimum with increasing deposition substrate temperature. From the current-voltage (I-V) characteristics of the TaOx thin films as a function of deposition substrate temperature, we found that the leakage current density in the TaOx thin films increases with increasing deposition substrate temperature. The higher leakage current density in the TaOx films is correlated to the oxygen deficiency in TaOx films and crystallization at higher deposition temperature. (C) 2003 Elsevier Ltd. All rights reserved.