期刊
JOURNAL OF LUMINESCENCE
卷 105, 期 2-4, 页码 117-119出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S0022-2313(03)00116-9
关键词
La3F3[Si3O9]; 5d-configuration; Ce3+; centroid shift
类别
A model that predicts the energy of the barycenter of the 5d configuration of Ce3+ in oxides and fluorides is applied to La3F3[Si3O9]:Ce3+. Because the lattice relaxation around Ce3+ is rather insignificant, this is an ideal compound to verify if the model also holds when Ce3+ is coordinated by two different types of anions. A very good agreement with the experimental value of 1.00 eV is obtained. The model predicts that the three coordinating fluorine ions contribute 0.14 eV and the eight oxygen ions 0.90 eV to the total centroid shift. (C) 2003 Elsevier B.V. All rights reserved.
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