期刊
EUROPEAN PHYSICAL JOURNAL B
卷 36, 期 3, 页码 349-357出版社
SPRINGER-VERLAG
DOI: 10.1140/epjb/e2003-00353-6
关键词
-
Photon correlation data of the molecular glass-forming materials 2-picoline, dimethylphthalate (DMP) and salol are compared with their dielectric loss spectra in the time-frequency range where the dielectric data reveal secondary relaxations. Slow secondary relaxation processes in molecular liquids are commonly studied by dielectric spectroscopy (DS) and, based on such studies, believed to be characteristics of the deeply super-cooled liquid state. However, there has been no direct experimental evidence that they are similarly detected by other experimental techniques. In the present study, we experimentally address this question for the anisotropic (depolarized) light scattering (LS). In the first approximation, DS and LS probe the same molecular reorientation dynamics, and therefore are expected to provide qualitatively similar spectra. We find however that this is not the case, namely i) the magnitude of the slow secondary relaxations is much less in LS than in DS data, which is the opposite to expectations; ii) the shape of the relaxation spectrum is qualitatively different, concerning both the main and secondary processes. We discuss possible sources of these differences in the context of related data from the literature.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据