Thermal and mechanical characterization of linear low density polyethylene/wood flour composites

A linear low-density polyethylene (LLDPE) matrix was modified with an organic peroxide and by a reaction with maleic anhydride (MAn) and was simultaneously compounded with untreated wood flour in a twin-screw extruder. The thermal and mechanical properties of the modified LLDPE and the resulting composites were evaluated. The degree of crystallinity was reduced in the modified LLDPE, but it increased with the addition of wood flour for the formation of the composites. Significant improvements in the tensile strength, ductility, and creep resistance were obtained for the MAn-modified composites. This enhancement in the mechanical behavior could be attributed to an improvement in the compatibility between the filler and the matrix. (C) 2003 Wiley Periodicals, Inc.